Differential Electrochemical Mass Spectrometry (DEMS) is an analytical technique that combines electrochemical half-cell experimentation with mass spectrometry. It allows in situ mass resolved determination of gaseous or volatile electrochemical reactants, reaction intermediates and products in real time. Hiden Analytical offer a range of DEMS cells with electrolyte/nanoporous sampling interface to the Hiden HPR-40 DSA Mass Spectrometer.
For applications where online electrochemical MS, OEMS, from an existing cell or reactor is required, a range of standard inlet options is available offering both evolved off-gas and dissolved species analysis solutions. Electrochemical cells that can be interfaced to the Hiden HPR-40 DEMS system include selected models from: Redoxme AB, and EL-Cell®
DEMS cell – A differentially pumped mass spectrometry inlet for in situ mass resolved determination of gaseous or volatile electrochemical reactants, reaction intermediates and products in real time.
The system includes:
- Quadrupolemass spectrometer system from the RGA series or high performance 3F series, with mass range options 200 or 300 a
- MASsoftProfessional PC softwar
- Massspectrometer analyser manifold and UHV pump set.
- DEMScell inlet kit including two DEMS cells, differential pumping, isolation valve with interlock and variable leak val
- Totalpressure gauge and interlocks to provide protection for the mass spectrometer in case of over pressur
- Integrationeither as a bench mounted module or a mobile cart.
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